The magnitude and spatial variability of CO2 surface emissions and processes involving CO2 released to the atmosphere from the soils are relevant issues in the context of climate change. This work evaluated CO2 fluxes and 13C/12C ratio of vegetation, organic matter, and soil gases from no disturbed soils of Chaco Pampean Plain (Argentina) with different soil properties and environmental conditions (PL and PA units). Soil organic decomposition from individual layers was accompanied by δ13C of total organic carbon (δ13C-TOC) values more enriched to depth. δ13C-TOC values in the upper soil profile ~ ca. 0–15 cm were like the plant community of this area (~−33 to −29 ‰) while δ13C-TOC varied stronger bellow horizon A, till ~ −24‰. Both δ13C-TOC and soil δ13C-CO2 were similar (~ −24 to 26 ‰) at deeper horizons (~ 50–60 cm). Toward the superficial layers, δ13C-TOC and δ13C-CO2 showed more differences (till ~ 4 ‰), due influence of the diffusion process. Horizon A layer (~ 0–20 cm) from both PL and PA units contained the most enriched δ13C-CO2 values (~ −15–17 ‰) because atmospheric CO2 permeated the soil air. A simple two-component mixing model between sources (atmospheric δ13C-CO2 and soil CO2) confirmed that process. Isotopically, CO2 fluxes reflected the biodegradation of C3 plants (source), diffusive transport, and CO2 exchange (atmosphere/soil). Soil moisture content appeared as a determining factor in the diffusion process and the magnitude of CO2 surface emissions (12–60 g·m−2·d−1). That condition was confirmed by CO2 diffusion coefficients estimated by air-filled porosity parameters and soil radon gradient model.

The 50 m-thick Berriasian organic-rich interval (BORI) of the Vaca Muerta Formation (Neuquén Basin, Argentina) represents one of the most attractive stratigraphic intervals for unconventional hydrocarbon exploration in the unit. Nevertheless, little is known about the environmental conditions prevailing during the accumulation of the sediments. To unravel the causes that favored the preservation of the organic matter (OM) in the BORI, a detailed multiproxy sedimentological approach was conducted. The study included the analyses of microfacies, palynological content, calpionellid-calcisphere dinocysts, mineralogy, spectral gamma-ray, inorganic geochemistry, Rock-Eval pyrolysis and stable carbon isotopes of whole rock carbonate (δ13Ccarb), and associated OM (δ13Corg). The BORI presents a late Early to early Late Berriasian age and is subdivided into a lower and upper interval. The lower interval (25.6 m-thick) is primarily formed by radiolaritic wackestones and presents higher total organic carbon (TOC) content (4.2 wt% on average), mainly in the form of amorphous OM (AOM), with variable contribution of phytoclasts. The geochemical analyses (Si, Ni, Cu, Mo, U, V) indicate high productivity of the water column and overall sea bottom anoxia. Oppositely, the upper interval (24.4 m-thick) is mostly constituted by peloidal packstones/grainstones and presents a lower TOC content (1.5 wt% on average) mainly constituted by phytoclasts, with variable contribution of AOM. A decrease of the productivity and an increase of sea bottom oxygenation is recorded based on the geochemical analyses. The high OM content of the BORI responds to the combination of high productivity of the water column and sea bottom anoxia in response to the Berriasian transgression and a worldwide paleoclimatic change towards more humid conditions. The results of our study position the BORI as an attractive interval for unconventional hydrocarbon production due to its high TOC, low bulk clay mineral and high biogenic quartz content, granting an adequate geomechanical behavior.

The North Scotia Ridge is the offshore morphostructural expression of the left-lateral transcurrent South America–Scotia plate boundary. Several blocks make up the ridge, including the scarcely studied Namuncurá Bank (also known as the Burdwood Bank). We present the first detailed study of active structures on the seafloor of the western Namuncurá Bank from a database of 3D and 2D seismic data, multibeam bathymetry and sub-bottom profiles. This work assesses the architecture, style of deformation and Cenozoic evolution of Namuncurá Bank, where several groups of faults and en echelon folding affect the seabed and shallow sub-bottom. These features compound the northernmost structures associated with a releasing bend, fitting well with a left-lateral Riedel shear model oriented at N74°E, slightly rotated with respect to the present day plate boundary stress regime. The current tectonic scenario started with a main deformational phase in the Neogene, partially distributed by the Malvinas fold–thrust belt, while modern deformation continues to be conditioned by pre-existing structures. This study allows a better understanding of the tectonics of the North Scotia Ridge, a morphostructure that influences the circulation of the Antarctic Circumpolar Current, thus impacting the global climate.

Lago Viedma is a proglacial lake into which the Viedma Glacier flows from the Southern Patagonian Ice Field. This glacier has rapidly lost mass in recent times, and its deglacial history is reflected in the lake's subsurface. New high-resolution multi-channel seismic profiles acquired in the northwestern sector of the lake have allowed us to reconstruct the bathymetry of the area and identify several small sub-basins, which have a maximum depth of 240 m in this sector. Four seismic facies have been recognized, separated by erosional unconformities, reflecting the depositional conditions in this sector of the basin during different Quaternary sedimentation phases. There is a transitional phase from ice-contacted deposits to subglacial deposits, probably associated with a subglacial fan, and finally a phase of lacustrine sedimentation. In addition, three depositional stages were identified within the lacustrine deposits, indicating a different sedimentary input, and the morphologies observed at the lake bottom suggest the existence of at least ten stagnations of the glacial margin. This study helps to improve the history of the retreat of the Viedma Glacier in this area during the Pleistocene/Holocene and provides a basis for further geophysical measurements aimed at mapping this remote lacustrine environment.

The deep ocean comprises complex ecosystems made up of numerous community and habitat types that provide multiple services that benefit humans. As the industrialization of the deep sea proceeds, a standardized and robust set of methods and metrics need to be developed to monitor the baseline conditions and any anthropogenic and climate change-related impacts on biodiversity, ecosystem function, and ecosystem services. Here, we review what we have learned from studies involving offshore-energy industries, including state-of-the-art technologies and strategies for obtaining reliable metrics of deep-sea biodiversity and ecosystem function. An approach that includes the detection and monitoring of ecosystem services, with open access to baseline data from multiple sectors, can help to improve our global capacity for the management of the deep ocean.

The La Veteada Formation, in the Sierra de Famatina (west of Argentina), is one of the few records of Early Triassic age in South America verified by isotopic age and palynological assemblages. This unit is composed of sandstones, mudstones, shales, limestones, and marls, with some levels of gypsum, chert, and tuff levels. In its stratotype, the La Veteada Formation rests on Late Permian red beds of the Talampaya Formation and is covered by Neogene breccias and conglomerates belonging to the Del Crestón Formation. The unit is divided into three associations of sedimentary facies. Facies association A (80 m thick) is a red bed succession composed of mudstone and fine-grained sandstone, together with some levels of chert and gypsum. Facies association B (58 m thick) is greenish-gray to yellowish-gray and comprises limestones, marls, shales, and fine- to coarse-grained sandstones. This facies includes stromatolites and several levels of shales and marls where rich palynological assemblages were recovered. Finally, facies association C (24 m thick) is made up of yellowish-gray marls, mudstones, and sandstones. In this section, stromatolites are missing, thin levels of gypsum appear, and evidence of subaerial exposition as mud cracks and raindrop imprints are frequent at the top of the facies. The lithology, sedimentary structures, and vertical stacking of facies suggest that the La Veteada Formation was deposited in a lacustrine environment, which evolved from a shallow ephemeral playa lake system (facies association A) to a perennial lake, in which carbonate production increased compared to clastic sedimentation (facies association B). Regarding the facies association C, the increase in clastic supply, the missing stromatolites, and the presence of gypsum levels suggest a progressive shallowing of the lake and the likely transition to a palustrine environment. The Early Triassic age of the La Veteada Formation is indicated from two different lines of research. Firstly, a zircon U-Pb age of 249.66±0.11 Ma obtained from a tuff level at the middle part of the facies association A. Secondly, the presence of palynological species identified in other Early Triassic units worldwide. The La Veteada Formation records the filling of the embryonic extensional basins formed at the earliest Triassic. Moreover, this unit shows the evolution of depositional environments after the late Permian massive extinction event.

The Eocene compressional phase is well known to have contributed to the construction of the Andes orogen at latitudes north of 30° S, but its extension to the south has not been fully studied. Moreover, synorogenic deposits of Eocene age across the foreland are scarce. The Cenozoic Manantiales Basin records the unroofing sequence of the Andes at 32° S. This study focuses on the basal infill of the Manantiales Basin, informally called the Areniscas Chocolate, which has received less attention than the upper infill until now. Sedimentological, geochronological and provenance studies were carried out on this unit. Here, we present the first ages for the Areniscas Chocolate sequence, of ca. 35–39 Ma (maximum depositional age, MDA). This MDA is interpreted as close to its depositional age, which together with their stratigraphic characteristics, allow us both to separate it from the overlying Miocene Chinches Formation and to propose it as an independent lithostratigraphic unit called Río de los Patos Formation (nov. den.). The provenance analysis of the Río delos Patos Formation indicates a sediment input from western sources located in the Coastal Cordillera and Western Principal Cordillera. Facies associations suggest that the Río de los Patos Formation represents the distal synorogenic deposits during the construction of an Eocene relief to the west. Therefore, the Manantiales Basin started during the late Eocene as a distal foreland basin, indicating that Eocene compression reached latitudes as far south as 32° S. Our results shed light into the characterization of the earliest infill of the Manantiales Basin, as well as into the tectonic evolution of the basin.

In Tierra del Fuego, the Magallanes-Fagnano Fault System (MFFS) accommodates a significant portion of the relative motion between the South America and Scotia plates. However, it remains unclear whether some of the deformation is partitioned southwards, along the Beagle Channel Fault System (BCFS). In this paper, high-resolution seismic reflection profiles were used to identify fault-related ruptures in the submerged Quaternary sediments of the Beagle Channel. Some faults reach the seafloor, affecting marine sediments, indicating they are Holocene in age. The correlation with outcrop data and lineaments mapped onshore suggests the post-glacial reactivation of two structures: the E-W striking BCFS and the NW-SE-trending Lapataia Fault Zone (LFZ). Whereas the BCFS displays along-strike variation in throw, the LFZ shows significant normal displacements. These results imply that deformation occurs in a wider and more complex manner than previously thought and highlight the need for a thorough hazard assessment of the area.

including turtles, crocodiles, and mammals. The age of this unit is currently under discussion given the lack of absolutechronological data, although recent works favored a middle Paleocene–early Eocene age. In this contribution, we present a leftmaxillary fragment (PVL 5901), preserving part of the M1 and the M2. A first analysis indicates a close relationship with Indalecia(Litopterna?, Indaleciidae), a genus previously recorded for the Lower Lumbrera Formation (?Ypresian; Salta Province, northwesternArgentina). Given that the Indaleciidae and the representatives of Amilnedwardsidae and Notonychopidae were considered relatedin the context of the order Notopterna, a comparison was made between PVL 5901 and these taxa, confirming its resemblancewith Indalecia. However, PVL 5901 differs from Indalecia grandensis(type and only species of the genus) by the presence of acuspule on the base of the ectoflexus, the absence of a small fossette mesial to the distolabial fossette, and a conspicuousentoflexus. Hence, we refer PVL 5901 to Indaleciasp. This is the first common faunal element between the Río Loro and LowerLumbrera formations. Nevertheless, the marked taxonomic discrepancies between the Río Loro vertebrate assemblage and otherearly Paleogene units contrast with this single common record, and a partial temporal correspondence between the Río Loro andLower Lumbrera formations is not supported here. Instead, this record indicates a more extended temporal and geographicaldistribution for the genus Indaleciain northwestern Argentina.Key words. Río Loro Formation. Lower Lumbrera Formation. Notopterna. Biostratigraphy. Northwestern Argentina.Resumen.